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If you are planning on using your Office 365 Exchange Account within Outlook 2013, then you will need to first make sure that you have downloaded Office 2013 and have install all updates.
Then go ahead and bring up your Control Panel.
Within the Control Panel window, click on the search bar and type “Mail”. Click on Mail (Microsoft Outlook 2013).
Next click on Show Profiles then click on Add.
Go ahead and enter a name for your New Profile. Next you will be asked to enter the information for your Exchange Account. Enter your Name, your Email Address and your Password.
Click Next, Outlook 2013 will begin trying to locate your Office 365 Exchange account information. Once it successfully configures your account click Finish. You have now successfully configured your Office 365 Exchange account on Outlook 2013.